The law related to maintenance is provided under section 125 of th CRPC (now section 144 of the BNSS). The numbering of the section has got changed while the law remains same. As per the law, the wife is not entitled for maintenance or interim maintenance and expenses of proceeding from her husbands if she is living in adultry, or if, without any sufficient reason she refuses to live with her husband, or that they are living separately by mutual consent.
The picture of your sister has been posted in a public platform. The husband may use it agaisnt your sister. But it is very difficult to prove adultry with only a picture. Further, the law is not concern with the past of wives, but present. This means the husband needs to prove that the wife is presently lving in adultry.